- saddler (3 people)
- saddlery manufacturer (6 people)
- sailor/wran (11 people)
- salt manufacturer (5 people)
- Salvation Army officer (12 people)
- sanitary engineer (15 people)
- satirist (11 people)
- sawmiller (31 people)
- sawyer (1 person)
- school administrator (8 people)
- school inspector (73 people)
- school owner (59 people)
- school principal (300 people)
- schoolteacher (488 people)
- scientific instrument maker (6 people)
- scriptwriter (11 people)
- sculler (10 people)
- sculptor (40 people)
- sealer (16 people)
- secularist (16 people)
- seedsman (5 people)
- seismologist (3 people)
- selector (21 people)
- Semitic scholar (2 people)
- separationist (103 people)
- sericulturist (4 people)
- service station/garage owner (5 people)
- set designer (6 people)
- sex reformer (12 people)
- Shakespearean scholar (9 people)
- shearer (27 people)
- sheep breeder (162 people)
- sheepdog expert (3 people)
- shell collector (9 people)
- ship chandler (2 people)
- ship repairer (1 person)
- ship's pilot (7 people)
- ship's providore (1 person)
- ship's surgeon (40 people)
- shipbuilder (25 people)
- shipowner (141 people)
- shipping agent (53 people)
- shipwright (6 people)
- shoe/boot maker (8 people)
- shoe/boot manufacturer (18 people)
- shooter (competitive) (12 people)
- short story writer (130 people)
- show judge/administrator (14 people)
- showman (9 people)
- silver, lead, zinc mine manager (15 people)
- silver, lead, zinc mine owner (17 people)
- silver, lead, zinc miner (12 people)
- silversmith (6 people)
- singer (16 people)
- singing teacher (22 people)
- single taxer (12 people)
- sinologist (1 person)
- ski instructor (1 person)
- skier (competitive) (3 people)
- skiing promoter (1 person)
- sly-grog operator (2 people)
- snooker player (2 people)
- soap and/or candle manufacturer (15 people)
- soccer administrator (2 people)
- soccer player (1 person)
- social historian (2 people)
- social reformer (50 people)
- social welfare analyst (3 people)
- social worker (8 people)
- socialist (97 people)
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